A versatile environmental control cell for in situ guest exchange single-crystal diffraction

Abstract

In situ single-crystal diffraction experiments provide researchers with the opportunity to study the response of crystalline systems, including metal–organic frameworks and other nanoporous materials, to changing local microenvironments. This paper reports a new environmental control cell that is remarkably easy to use, completely reusable, and capable of delivering static or dynamic vacuum, liquids or gases to a single-crystal sample. Furthermore the device is nearly identical in size to standard single-crystal mounts so a full unrestricted range of motion is expected for most commercial goniometers. In situ single-crystal X-ray diffraction experiments performed under dynamic gas-flow conditions revealed the cell was capable of stabilizing a novel metastable intermediate in the dehydration reaction of a previously reported metal–organic framework.

Jordan M. Cox,a Ian M. Walton,a Cassidy A. Benson,a Yu-Sheng Chenb and Jason B. Benedicta*

aDepartment of Chemistry, University at Buffalo, SUNY, Natural Sciences Complex, Buffalo, NY 14260-3000, USA, and bChemMatCARS, Center for Advanced Radiation Sources, 9700 South Cass Avenue, Building 434D, Argonne, IL 60532, USA
*Correspondence e-mail: jbb6@buffalo.edu

 

DOI: 10.1107/S160057671500432X 

J. Appl. Cryst. (2015). 48, 578–581